Sunday, May 20, 2007

Battery working Principle

Batteries are all over the place -- in our cars, our PCs, laptops, portable MP3 players and cell phones. A battery is essentially a can full of chemicals that produce electrons. Chemical reactions that produce electrons are called electrochemical reactions. From the basic concept at work to the actual chemistry going on inside a battery to what the future holds for batteries and possible power sources that could replace them!
If you look at any battery, you'll notice that it has two terminals. One terminal is marked (+), or positive, while the other is marked (-), or negative. In an AA, C or D cell (normal flashlight batteries), the ends of the battery are the terminals. In a large car battery, there are two heavy lead posts that act as the terminals.

Electrons collect on the negative terminal of the battery. If you connect a wire between the negative and positive terminals, the electrons will flow from the negative to the positive terminal as fast as they can (and wear out the battery very quickly -- this also tends to be dangerous, especially with large batteries, so it is not something you want to be doing). Normally, you connect some type of load to the battery using the wire. The load might be something like a light bulb, a motor or an electronic circuit like a radio. Inside the battery itself, a chemical reaction produces the electrons. The speed of electron production by this chemical reaction (the battery's internal resistance) controls how many electrons can flow between the terminals. Electrons flow from the battery into a wire, and must travel from the negative to the positive terminal for the chemical reaction to take place. That is why a battery can sit on a shelf for a year and still have plenty of power -- unless electrons are flowing from the negative to the positive terminal, the chemical reaction does not take place. Once you connect a wire, the reaction starts.

The first battery was created by Alessandro Volta in 1800. To create his battery, he made a stack by alternating layers of zinc, blotting paper soaked in salt water, and silver, like this:

This arrangement was known as a voltaic pile. The top and bottom layers of the pile must be different metals, as shown. If you attach a wire to the top and bottom of the pile, you can measure a voltage and a current from the pile. The pile can be stacked as high as you like, and each layer will increase the voltage by a fixed amount.

In the 1800s, before the invention of the electrical generator (the generator was not invented and perfected until the 1870s), the Daniell cell (which is also known by three other names -- the "Crowfoot cell" because of the typical shape of the zinc electrode, the "gravity cell" because gravity keeps the two sulfates separated, and a "wet cell," as opposed to the modern "dry cell," because it uses liquids for the electrolytes), was extremely common for operating telegraphs and doorbells. The Daniell cell is a wet cell consisting of copper and zinc plates and copper and zinc sulfates.
To make the Daniell cell, the copper plate is placed at the bottom of a glass jar. Copper sulfate solution is poured over the plate to half-fill the jar. Then a zinc plate is hung in the jar as shown and a zinc sulfate solution poured very carefully into the jar. Copper sulfate is denser than zinc sulfate, so the zinc sulfate "floats" on top of the copper sulfate. Obviously, this arrangement does not work very well in a flashlight, but it works fine for stationary applications. If you have access to zinc sulfate and copper sulfate, you can try making your own Daniell cell.

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